Channel 16 and channel 70
Channel 16 (156.800 MHz) is the international distress, safety and calling channel, and every vessel with a VHF should listen on it while at sea. After making contact on 16, move to a working channel. Channel 70 (156.525 MHz) carries digital selective calling (DSC) only. A DSC radio connected to GPS can send a distress alert with your position at the press of a button. Voice is never used on 70.
Simplex and duplex
Simplex channels use one frequency, so ships can talk to each other. Duplex channels use a pair: the ship transmits on the lower frequency and the coast station 4.6 MHz higher, which allows telephone-style conversation with a coast station but not between ships. In the US, many duplex channels are used in simplex on the ship frequency, called "A" channels, such as 22A (157.100 MHz) for the US Coast Guard.
Licences
In the UK, a fixed or handheld marine VHF needs a free Ofcom Ship Radio Licence or Ship Portable Radio Licence, and the operator needs a Short Range Certificate (SRC). In the US, recreational boats in US waters don't need a station licence, but DSC radios need an MMSI number. Marine VHF is for use on the water, and using it on land is only allowed for licensed coast stations.
Range
VHF is line of sight, so range depends on antenna height. A handheld at deck level reaches about 5 nautical miles to another boat, and a masthead antenna 15 to 25 miles, further to a coastguard station on a hill. The link budget calculator works out the radio horizon for any antenna height.
Questions
What is marine VHF channel 16?
156.800 MHz, the international distress, safety and calling channel.
Which channel do I use to call the coastguard in the UK?
Channel 16 for distress and urgency. For routine safety calls, call on 16 and you'll be moved to a working channel such as 67.
What is channel 13 used for?
Bridge-to-bridge navigation safety between ships, at 1 W.
Do I need a licence for a handheld marine VHF?
In the UK, yes: a free Ship Portable Radio Licence from Ofcom, and an operator's certificate such as the SRC.